Biphenyl-3,3′,5,5′-tetracarboxylic acid

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Biphenyl-3,3′-dicarb­oxy­lic acid

The asymmetric unit of the title compound, C(14)H(10)O(4), contains one half mol-ecule, the complete mol-ecule being generated by a twofold axis. The two benzene rings form a dihedral angle of 43.11 (5)°. Inter-molecular O-H⋯O hydrogen bonds link the mol-ecules into one-dimensional zigzag chains. These chains are further connected into two-dimensional supra-molecular layers by weak π-π stacking...

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Enhancement of CO2 Adsorption and Catalytic Properties by Fe-Doping of [Ga2(OH)2(L)] (H4L = Biphenyl-3,3′,5,5′-tetracarboxylic Acid), MFM-300(Ga2)

Metal-organic frameworks (MOFs) are usually synthesized using a single type of metal ion, and MOFs containing mixtures of different metal ions are of great interest and represent a methodology to enhance and tune materials properties. We report the synthesis of [Ga2(OH)2(L)] (H4L = biphenyl-3,3',5,5'-tetracarboxylic acid), designated as MFM-300(Ga2), (MFM = Manchester Framework Material replaci...

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1,1′-Biphenyl-2,3,3′,4′-tetra­carboxylic acid monohydrate

In the organic molecule of the title compound, C(16)H(10)O(8)·H(2)O, the dihedral angle between the two benzene rings is 42.30 (11)°. Extensive O-H⋯O hydrogen bonding helps to stabilize the crystal structure.

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3,3′-[Biphenyl-4,4′-diylbis(­oxy)]diphthalic acid

In the title mol-ecule, C(28)H(18)O(10), the two central benzene rings form a dihedral angle of 31.0 (1)°. In the phthalic acid fragments, the carb-oxy groups in the meta positions are approximately coplanar with the attached benzene rings, being inclined to their planes at 2.7 (1) and 10.3 (1)°, while the carb-oxy groups in the ortho positions are twisted from the benzene ring planes by 83.5 (...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2002

ISSN: 1600-5368

DOI: 10.1107/s1600536802008206